WebChemical structures of the phosphazene bases t-BuP 1 , t-BuP 2 and t-BuP 4. The values in the parentheses indicate the pK a in acetonitrile. Source publication Anionic Polymerization of... WebFeb 27, 2024 · The P1−N1 distance is 1.801(2) Å, which is somewhat longer than a typical N−P single bond (1.70–1.74 Å). 29 The P1-N1 bond is also longer than the P2-N2 distance, which can be an indication of some contribution of the resonance form 9’’ (Scheme 1) that can be regarded as an iminophosphinyl-substituted phosphinidene, stabilized by an ...
An Investigation of the Organoborane/Lewis Base Pairs on the ...
Phosphazene bases are strong non-metallic non-ionic and low-nucleophilic bases. They are stronger bases than regular amine or amidine bases. Protonation takes place at a doubly bonded nitrogen atom. Related to phosphazene bases are the Verkade bases, which feature P(III) with three amido substituents and a transannular amine. The pKa's of tert-Bu−(H)N=P(−N=P(−NR2)3)3] , where R = Me WebJan 8, 2024 · Using TEB/t-BuP1pair with the molar ratio of 4/1 at 80 °C, the turnover of frequency (TOF) was up to 128 h-1and clearly higher than the known TOF values (0.5-34 h-1) of the PO/SA copolymerization by previously reported catalysts. howard family dental hinesville ga
Phosphazene base P1-t-Bu = 97.0 GC 81675-81-2 - Sigma-Aldrich
WebPhosphazene base P1-t-Bu ≥97.0% (GC) Synonym (s): tert-Butylimino-tris (dimethylamino)phosphorane, N′-tert-Butyl-N,N,N′,N′,N″,N″-hexamethylphosphorimidic triamide Empirical Formula (Hill Notation): C10H27N4P CAS Number: 81675-81-2 Molecular Weight: 234.32 Beilstein: 4178783 MDL number: MFCD00145111 PubChem Substance ID: … WebP4-t-Bu is a readily accessible chemical from the group of neutral, peralkylated sterically hindered polyaminophosphazenes, which are extremely strong bases but very weak … WebPhosphazene base P1-t-Bu (CAS 81675-81-2) Write a review Ask a question Alternate Names: tert-Butylimino-tris (dimethylamino)phosphorane CAS Number: 81675-81-2 Purity: … how many inches of snow are we getting monday